Glossary entry

English term or phrase:

ashing aid

Portuguese translation:

método de calcinação

Added to glossary by Sidnei Arruda
May 30, 2012 20:14
12 yrs ago
3 viewers *
English term

ashing aid

English to Portuguese Tech/Engineering Engineering: Industrial
If digestion is necessary, use acid digestion, ensuring no residual oxidizing acid is present (see 'Oxidation States' on Page 57, or ashing with an appropriate ashing aid. Simple dry ashing is not recommended.
...
If digestion is necessary, use acid digestion, or ashing with an appropriate ashing aid.
Simple dry ashing is not recommended as the mercury will be lost.

Discussion

airmailrpl May 30, 2012:
Ashing products Ashing products are often dissolved and subjected to further analysis such as ICP and low recoveries can be a result of incomplete ash dissolution. Sulfating the char forms metal sulfates. Typically, you could use a 1:1:2 mixture of HCl:HNO3:H2O to dissolve the ash.

Wet Ashing:

Advantages: Little loss of volatile minerals occurs because of the lower temperatures used, more rapid than dry ashing.

Disadvantages: Labor intensive, low sample throughput. Typically, a digestion takes from 10 minutes to a few hours at temperatures of about 350oC-450oC. The resulting solution can then be analyzed for species of interest.

http://www.chemicalforums.com/index.php?topic=22074.0
airmailrpl May 30, 2012:
ashing If we are talking about ashing techniques for metals-then that would depend on where the formation of sulfates is important to your analysis:

Dry Ashing: Performed by placing the sample in an open inert vessel and destroying the combustible (organic) portion of the sample by thermal decomposition using a muffle furnace. Ashing temperatures usually range from 450 to 550oC. Magnesium nitrate is a common ashing aid. Usually, the sample is charred prior to muffling. Charring is accomplished using an open flame (crucibles/clay triangles/Bunsen and/or Meeker burners under a hood).

Wet Ashing: Samples are treated with a small to moderate amount of sulfuric acid prior to charring. The charring is performed using an open flame (crucibles/clay triangles/Bunsen and/or Meeker burners under a hood).. Liquid samples have a tendancy to foam. After the excess sulfuric acid is driven off, the sample is muffled from 450 to 550oC.

For example: Charring and ashing can form metal oxides. The objective is to keep the temperature on the low side (approx. 450oC). Metal oxides can be very difficult to dissolve.

http://www.chemicalforums.com/index.php?topic=22074.0

Proposed translations

34 mins
Selected

método de decomposição/calcinação

Creio que "aid", no contexto se refere ao método.


http://www.proz.com/kudoz/english_to_portuguese/chemistry;_c...


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Note added at 1 hr (2012-05-30 21:31:36 GMT)
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Process Assurance

According to IEEE, quality assurance is defined as "a planned and systematic pattern of all actions necessary to provide adequate confidence that an item or product conforms to established technical requirements." Quality assurance (QA) can be broken down into two main areas: product assurance and process assurance

http://www.hq.nasa.gov/office/codeq/software/ComplexElectron...

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Note added at 1 hr (2012-05-30 21:32:34 GMT)
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FAVOR IGNORAR A A REFERÊNCIA ACIMA. (PROCESS ASSURANCE)

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Note added at 1 hr (2012-05-30 21:34:28 GMT)
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Métodos de decomposição por via seca ou úmida


Dry Ashing is usually performed by placing the sample in an open inert vessel and destroying the combustible (organic) portion of the sample by thermal decomposition using a muffle furnace. Typical ashing temperatures are 450 to 550 °C. Magnesium nitrate is commonly used as an ashing aid. Charring the sample prior to muffling is preferred. Charring is accomplished using an open flame.

Wet Ashing is treatment of the sample with a moderate amount of sulfuric acid before charring. Charring is performed using an open flame. Liquid samples tend to foam. After the excess sulfuric acid is driven off, the sample is muffled as above.
Jeovane Cazer

Métodos de decomposição por via seca ou úmida
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4 KudoZ points awarded for this answer. Comment: "obrigado a todos"
47 mins

auxiliar de redução a cinzas, coadjuvante de calcinação

EN

ashing aid

ES

coadyuvante de calcinación

PT

auxiliar de redução a cinzas

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1 hr

agente incinerador

Sugestão.
Agente incinerador (ou calcinante).
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1 hr

modificador químico de decomposição

ashing aid => modificador químico de decomposição

Química Nova - Solid sampling graphite furnace atomic absorption ...
www.scielo.br/scielo.php?pid=S0100...script... -
A adição de uma alíquota de modificador químico em solução sobre a amostra ... possuem elevada pureza ou são caracteristicamente de difícil decomposição.

EspEctromEtria dE absorção atômica: o caminho para ...
www.scielo.br/pdf/qn/v31n7/v31n7a33.pdf -
2008 - Related articles
crevia a decomposição e recomposição da luz do sol por um prisma. Daí por diante ..... Com o emprego da mistura da Pd e Mg como modificador químico ...

UNIVERSIDADE FEDERAL DE ALAGOAS FACULDADE DE - INÍCIO
www.bdtd.ufal.br/tde_busca/processaArquivo.php?... -
obtenção de cinzas isentas de carvão foi utilizado como “ashing-aid” 8 mL de ácido nítrico concentrado (HNO3 65%). Posteriormente adicionou-se 1 mL de ...

PÓS-GRADUAÇÃO EM QUÍMICA: RESUMOS DE DISSERTAÇÕES ...
www.quimicanova.sbq.org.br/qn/.../v18_n2_15.p...
amostra com o uso da mistura HzSO4rHzOz como “ashing-aid". A amostra é aquecida em chapa elétrica até a secura, queimada em bico de Bunsen e levada ...

RIALA 1115.pmd
www.revista.ial.sp.gov.br/index.php?...
de ácido nítrico concentrado (“ashing aid”) e deixou-se até à secura sobre chapa aquecedora. Retornou-se à mufla à 4500C por 2 horas. Repetiu-se, em média, ...

dry ashing > Métodos de decomposição por via seca ou úmida ...
por.proz.com/...to.../1239308-dry_ashing.html -
25 jan. 2006 – ProZ.com - Diretório global de serviços de tradução .... temperatures are 450 to 550 °C. Magnesium nitrate is commonly used as an ashing aid.

DETERMINAÇÃO - Biblioteca do Instituto de Química - UNICAMP
biq.iqm.unicamp.br/arquivos/teses/000446162.pdf -
by LUE ATÔMICA - Related articles
(calcinação, digestão ácida à baixa e à alta temperatura e digestão assistida por microondas em ..... é removida com auxílio de uma interface, desta forma, os efeitos de auto absorção ...... O modificador químico utilizado foi uma solução de nitrato de magnésio e nitrato de ... amostra apresenta 3 etapas de decomposição.

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dry ashing > Métodos de decomposição por via seca ou úmida ...
www.por.proz.com/...to.../1239308-dry_ashing.html -
– Dry Ashing is usually performed by placing the sample in an open inert vessel and destroying the combustible (organic) portion of the sample by thermal decomposition using a muffle furnace. Typical ashing temperatures are 450 to 550 °C. Magnesium nitrate is commonly used as an ashing aid. Charring the sample prior to muffling is preferred. Charring is accomplished using an open flame.

Wet Ashing is treatment of the sample with a moderate amount of sulfuric acid before charring. Charring is performed using an open flame. Liquid samples tend to foam. After the excess sulfuric acid is driven off, the sample is muffled as above.
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